Aldehydes

Aldehydes

 





Aldehydes :


Fun. group formula




Fun. group name = Aldehyde OR formagroup

General formula : nH2no (n= 1,2,3...) or R-CHO


Defi : 

The aldehydes are organic compounds containing functional group -CHO (aldehyde) is called aldehydes.

Formaldehyde

Acetaldehyde



Nomenclature :

1) Common name system :

i) Find the common name of corresponding carboxylic acid.

ii) Replace 'ic acid' of an acid with aldehyde term.

iii) Use the prefixes n, Iso & neo whenever needed.

IUPAC system :

Rule no.1:

I) Select the longest carbon chain with -CHO group.

II) Count the number of carbon atoms in normal chain with carbon atom of -CHO.

III) Find the name of parent alkane.

IV) Replace ending 'e' alkane with 'al' suffix.

V) Thus it become 'alkanal'.

Rule No.2:

Start numbering to normal chain carbon atoms from carbon atom of -CHO group.

Rule No.3: 

Give the name & location of branched group.

Rule No. 4: If aldehyde contains 2,3,4 similar branched groups, use the prefixes di, tri & tetra respectively.

Rule No. 5: 

If aldehyde possesses different Branched groups , mention their name by alphabetical order.

 Sr. No.

  Formulae    

 Common name

  IUPAC name 

 1

 

  Formaldehyde

  methanal

 2

 

  Acetaldehyde

 ethanal

 3

 

  Propionaldehyde

  propanal

 4

 

  n.Butyraldehyde

 butanal 

 5

 

  n.Valeraldehyde

  pentanal

 6

 

  Isovaleraldehyde

  3-methylbutanal

 7

 

  Neovaleraldehyde

 2,2-dimethylpropanal 

 8

 

  Isocaproaldehyde

  Isocaproaldehyde

 9

 

  n-caproaldehyde

  hexanal

 10

 

  Neocaproaldehyde

  3,3-dimethylbutanal



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