ADSORPTION- Enthalpy of Adsorption, Adsorbate, Adsorbent, Specific surface area, Sorption,

ADSORPTION- Enthalpy of Adsorption, Adsorbate, Adsorbent, Specific surface area, Sorption,

Role of Adsorption in Surface Chemistry 

     
Accumulation of species on higher concentration on the surface of a substance due to intermolecular force is known as adsorption. 

      For Example:  Gages such as H2,  O2 , N adsorbs on the surface of activated charcoal.



Enthalpy of Adsorption :  Amount of heat energy liberated when one mole of gas is adsorbed on the unit surface area of adsorbent is known as enthaply of adsorption.


                                                      ADSORPTION  

* Adsorption is the phenomenon of attracting and retaining the molecules of substance on the surface of a liquid of solid, resulting in a higher concentration of molecules on the surface.
                                                     OR
* The attachment of particles to a surface is called Adsorption.
                                                     OR
* The phenomenon of concentration of molecules of a gas or liquid at a solid surface is called Adsorption. Adsorption is a surface phenomenon, Adsorption examples Alimina gel, silica gel, zeolites, activated carbon, graphite, finely divided metals, etc are some examples of good adsorbents.

* Adsorbate :-  The substance being adsorbed is called adsorbate.

 
* Adsorbent :-  The substance on whose surface it is being adsorbed is called adsorbent.




 Specific surface area :- Surface area of adsorbate per unit mass of adsorbent is known as specific surface area.

* Sorption  is a term used when both adsorption and adsorption occur simultaneously.


 Desorption is the reverse of adsorption, i. e. the removal of the adsorbed substance from the surface of the adsorbent.

* Occlusion is a term used for adsorption of gages on a metal surface.

* Positive adsorption occurs when concentration of adsorbate is more on surface of the adsorbent than in the bulk.

* Negative adsorption occurs when concentration of adsorbate on the surface of the adsorbent  is less than that in the bulk.

* Physical Adsorption or Physidorption is the process in which the adsorbate particles are held on the surface of adsorbent by weak van der Waal's surface.

* Chemical Adsorption or Chemisorption is the process in which the adsorbate molecules are held by the adsorbent by chemical forces.
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